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预制拼装箱梁现浇横隔梁水化热分析与控制研究

陈扬,钟瑶,郑开启,沈斌,孟少平

《中国工程科学》 2013年 第15卷 第8期   页码 99-103

摘要：

在节段预制拼装桥梁的墩顶节段，常常采用后浇横隔梁的方式来减轻吊装重量。后浇横隔梁在体量上属于大体积混凝土，混凝土水化热问题会引起一些部位拉应力过大，如控制措施不合理，往往会导致预制梁段在施工阶段的开裂。本文结合南京长江第四大桥的引桥工程，基于三维瞬态温度场理论，利用通用有限元程序ANSYS对墩顶梁段现浇块的水化热效应进行了数值仿真，研究箱梁水化热温度场和应力场的分布规律。分析结果表明，水化热引起的箱梁腹板外侧拉应力水平足以导致混凝土开裂，在水化热测试试验中也观测到了箱梁腹板外侧的纵向微裂缝，与分析相符。在研究水化热温度场和应力场分布规律的基础上，进行了控制水化热温度应力的措施研究，在实桥施工中证实是切实有效的。

关键词： 混凝土箱梁     水化热     温度场     应力场     裂缝    

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Hydration, microstructure and autogenous shrinkage behaviors of cement mortars by addition of superabsorbent

Beibei SUN, Hao WU, Weimin SONG, Zhe LI, Jia YU

《结构与土木工程前沿（英文）》 2020年 第14卷 第5期   页码 1274-1284 doi: 10.1007/s11709-020-0656-x

摘要： Superabsorbent Polymer (SAP) has emerged as a topic of considerable interest in recent years. The present study systematically and quantitively investigated the effect of SAP on hydration, autogenous shrinkage, mechanical properties, and microstructure of cement mortars. Influences of SAP on hydration heat and autogenous shrinkage were studied by utilizing TAM AIR technology and a non-contact autogenous shrinkage test method. Scanning Electron Microscope (SEM) was employed to assess the microstructure evolution. Although SAP decreased the peak rate of hydration heat and retarded the hydration, it significantly increased the cumulative heat, indicating SAP helps promote the hydration. Hydration promotion caused by SAP mainly occurred in the deceleration period and attenuation period. SAP can significantly mitigate the autogenous shrinkage when the content ranged from 0 to 0.5%. Microstructure characteristics showed that pores and gaps were introduced when SAP was added. The microstructure difference caused by SAP contributed to the inferior mechanical behaviors of cement mortars treated by SAP.

关键词： Superabsorbent Polymer     mechanical properties     hydration heat     autogenous shrinkage     microstructure    

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混凝土的裂缝与控制

缪昌文,刘建忠,田倩

《中国工程科学》 2013年 第15卷 第4期   页码 30-35

摘要：

在分析混凝土开裂的危害和产生原因的基础上，提出裂缝控制新技术。采用双亲性单分子膜，减少混凝土早期的水分蒸发，抑制混凝土早期因失水太快而产生的塑性收缩裂缝；采用减水与减缩共同作用，控制混凝土壳体及薄壁结构的早期开裂；采用调控水泥水化过程中的放热量，提高大体积混凝土的温控能力；采用遥爪聚合型增韧剂，增加混凝土的韧性，减少混凝土的脆性开裂。

关键词： 混凝土     裂缝     收缩     水化热     韧性    

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Thermodynamic analysis of ethanol synthesis from hydration of ethylene coupled with a sequential reaction

Jie Gao, Zhikai Li, Mei Dong, Weibin Fan, Jianguo Wang

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 847-856 doi: 10.1007/s11705-019-1848-6

摘要： Coal-based ethanol production by hydration of ethylene is limited by the low equilibrium ethylene conversion at elevated temperature. To improve ethylene conversion, coupling hydration of ethylene with a potential ethanol consumption reaction was analyzed thermodynamically. Five reactions have been attempted and compared: (1) dehydration of ethanol to ethyl ether ( ), (2) dehydrogenation of ethanol to acetaldehyde ( ), (3) esterification of acetic acid with ethanol ( ), (4) dehydrogenation of ethanol to ethyl acetate ( ), and (5) oxidative dehydrogenation of ethanol to ethyl acetate ( ). The equilibrium constants and equilibrium distributions of the coupled reactions were calculated and the effects of feed composition, temperature and pressure upon the ethylene equilibrium conversion were examined. The results show that dehydrogenation of ethanol to acetaldehyde has little effect on ethylene conversion, whereas for dehydrogenation of ethanol to acetaldehyde and ethyl acetate, ethylene conversion can be improved from 8% to 12.8% and 18.5%, respectively, under conditions of H O/C H = 2, 10 atm and 300°C. The esterification of acetic acid with ethanol can greatly enhance the ethylene conversion to 22.5%; in particular, ethylene can be actually completely converted to ethyl acetate by coupling oxidative dehydrogenation of ethanol.

关键词： ethylene     ethanol     thermodynamics     coupling    

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The effect of SiO

Ismael FLORES-VIVIAN, Rani G.K PRADOTO, Mohamadreza MOINI, Marina KOZHUKHOVA, Vadim POTAPOV, Konstantin SOBOLEV

《结构与土木工程前沿（英文）》 2017年 第11卷 第4期   页码 436-445 doi: 10.1007/s11709-017-0438-2

摘要： The nanoparticles of SiO were used in cement systems to modify the rheological behavior, to enhance the reactivity of supplementary cementitious materials, and also to improve the strength and durability. In this research, low-cost nano-SiO particles from natural hydrothermal solutions obtained by membrane ultrafiltration and, optionally, by cryochemical vacuum sublimation drying, were evaluated in portland cement based systems. ??The SiO -rich solutions were obtained from the wells of Mutnovsky geothermal power station (Far East of Russia). The constant nano-SiO dosage of 0.25% (as a solid material by weight of cementitious materials) was used to compare the cement systems with different nanoparticles against a reference mortar and a commercially available nano-SiO . Nanoparticles were characterized by X-Ray Diffraction (XRD), BET Surface Area, Scanning Electron Microscope (SEM) and Fourier Transform Infrared (FTIR) spectroscopy techniques. It was demonstrated that the addition of polycarboxylate ether superplasticizer and the dispersion treatment using an ultrasound processor can be used to facilitate the distribution of nano-SiO particles in the mixing water. The effect of nano-SiO particles in portland cement mortars was investigated by evaluating the flow, heat of hydration and compressive strength development. It was demonstrated that the use of nano-SiO particles can reduce the segregation and improve strength properties.

关键词： ultrafiltration     cryochemical vacuum sublimation drying     nanoparticles     portland cement     heat of hydration     surface area     compressive strength    

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Field test on temperature field and thermal stress for prestressed concrete box-girder bridge

Baoguo CHEN, Rui DING, Junjie ZHENG, Shibiao ZHANG

《结构与土木工程前沿（英文）》 2009年 第3卷 第2期   页码 158-164 doi: 10.1007/s11709-009-0002-9

摘要： A field test was conducted to investigate the distribution of temperature field and the variation of thermal stress for a prestressed concrete (PC) box-girder bridge. The change of hydration heat temperature consists of four periods: temperature rising period, constant temperature period, rapid temperature fall period and slow temperature fall period. The peak value of hydration heat temperature increases with the increasing casting temperature of concrete; the relation between them is approximately linear. According to field tests, the thermal stress incurred by hydration heat may induce temperature cracks on the PC box-girder. Furthermore, the nonlinear distribution of temperature gradient and the fluctuation of thermal stress induced by exposure to sunlight were also obtained based on continuous in-situ monitoring. Such results show that the prevailing Chinese Code (2004) is insufficient since it does not take into account the temperature gradient of the bottom slab. Finally, some preventive measures against temperature cracks were proposed based on related studies. The conclusions can provide valuable reference for the design and construction of PC box-girder bridges.

关键词： box-girder bridge     field test     hydration heat     temperature field     temperature gradient     thermal stress    

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Quantification of hydration products in cementitious materials incorporating silica nanoparticles

L. P. SINGH,A. GOEL,S. K. BHATTACHARYYA,G. MISHRA

《结构与土木工程前沿（英文）》 2016年 第10卷 第2期   页码 162-167 doi: 10.1007/s11709-015-0315-9

摘要： In the present work, silica nanoparticles (30-70nm) were supplemented into cement paste to study their influence on degree of hydration, porosity and formation of different type of calcium-silicate-hydrate (C-S-H) gel. As the hydration time proceeds, the degree of hydration reach to 76% in nano-modified cement paste whereas plain cement achieve up to 63% at 28 days. An influence of degree of hydration on the porosity was also determined. In plain cement paste, the capillary porosity at 1hr is ~48%, whereas in silica nanoparticles added cement is ~35 % only, it revealed that silica nanoparticles refines the pore structure due to accelerated hydration mechanism leading to denser microstructure. Similarly, increasing gel porosity reveals the formation of more C-S-H gel. Furthermore, C-S-H gel of different Ca/Si ratio in hydrated cement paste was quantified using X-ray diffractometer and thermogravimetry. The results show that in presence of silica nanoparticles, ~24% C-S-H (Ca/Si<1.0) forms, leading to the formation of polymerised and compact C-S-H. In case of plain cement this type of C-S-H was completely absent at 28 days. These studies reveal that the hydration mechanism of the cement can be tuned with the incorporation of silica nanoparticles and thus, producing more durable cementitious materials.

关键词： degree of hydration     porosity     calcium-silicate-hydrate (C-S-H)     silica nanoparticles    

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Absorption heat pump for waste heat reuse: current states and future development

Zhenyuan XU, Ruzhu WANG

《能源前沿（英文）》 2017年 第11卷 第4期   页码 414-436 doi: 10.1007/s11708-017-0507-1

摘要： Absorption heat pump attracts increasing attention due to its advantages in low grade thermal energy utilization. It can be applied for waste heat reuse to save energy consumption, reduce environment pollution, and bring considerable economic benefit. In this paper, three important aspects for absorption heat pump for waste heat reuse are reviewed. In the first part, different absorption heat pump cycles are classified and introduced. Absorption heat pumps for heat amplification and absorption heat transformer for temperature upgrading are included. Both basic single effect cycles and advanced cycles for better performance are introduced. In the second part, different working pairs, including the water based working pairs, ammonia based working pairs, alcohol based working pairs, and halogenated hydrocarbon based working pairs, for absorption heat pump are classified based on the refrigerant. In the third part, the applications of the absorption heat pump and absorption heat transformer for waste heat reuse in different industries are introduced. Based on the reviews in the three aspects, essential summary and future perspective are presented at last.

关键词： absorption     heat pump     heat transformer     waste heat     working pair    

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Effects of radiation and heat source/sink on unsteady MHD boundary layer flow and heat transfer over

Krishnendu Bhattacharyya

《化学科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 376-384 doi: 10.1007/s11705-011-1121-0

摘要： In this paper, an investigation is made to study the effects of radiation and heat source/sink on the unsteady boundary layer flow and heat transfer past a shrinking sheet with suction/injection. The flow is permeated by an externally applied magnetic field normal to the plane of flow. The self-similar equations corresponding to the velocity and temperature fields are obtained, and then solved numerically by finite difference method using quasilinearization technique. The study reveals that the momentum boundary layer thickness increases with increasing unsteadiness and decreases with magnetic field. The thermal boundary layer thickness decreases with Prandtl number, radiation parameter and heat sink parameter, but it increases with heat source parameter. Moreover, increasing unsteadiness, magnetic field strength, radiation and heat sink strength boost the heat transfer.

关键词： MHD boundary layer     unsteady flow     heat transfer     thermal radiation     heat source/sink     shrinking sheet     suction/injection    

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Heat-spreading analysis of a heat sink base embedded with a heat pipe

B. V. BORGMEYER, H. B. MA,

《能源前沿（英文）》 2010年 第4卷 第2期   页码 143-148 doi: 10.1007/s11708-010-0013-1

摘要： A simplified model predicting the heat transfer performance of a heat sink base with a high thermal conductivity was developed. Numerical analysis was performed using the commercial software FLUENT. The investigation indicates that for heat sink bases with a high effective thermal conductivity, such as the base embedded with a typical heat pipe, the entire heat sink can be modeled as a flat plate with a uniform temperature and an effective convection heat transfer coefficient. This simplified model can be used to determine the heat transfer performance of a heat sink embedded with a typical heat pipe or vapor chamber.

关键词： heat pipe     heat sink     microprocessor heat removal    

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Application of entransy dissipation theory in heat convection

Mingtian XU, Jiangfeng GUO, Lin CHENG,

《能源前沿（英文）》 2009年 第3卷 第4期   页码 402-405 doi: 10.1007/s11708-009-0055-4

摘要： In the present work, formulas for calculating the rates of the local thermodynamic entransy dissipation in convective heat transfer in general, and the internal and external flows in particular, are established. Practically, these results may facilitate the application of entransy dissipation theory in thermal engineering. Theoretically they shed light on solving the contradiction of the minimum entropy production principle with balance equations in continuum mechanics.

关键词： entransy dissipation     heat convection     heat exchanger    

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Effect of a commercial dispersion of multi walled carbon nanotubes on the hydration of an oil well cementing

Ocar Aurelio MENDOZA REALES,William C.PEARL Jr,Maria D. M. PAIVA,CristianeR. MIRANDA,Romildo Dias TOLEDO FILHO

《结构与土木工程前沿（英文）》 2016年 第10卷 第2期   页码 174-179 doi: 10.1007/s11709-015-0324-8

摘要： This work studies the influence of a commercial dispersion of multi wall carbon nanotubes (MWCNT) on the hydration of a class G cement paste, at room and elevated down-hole temperatures. The MWCNT dispersion was produced with a solids concentration of 3.0 % by mass and an anionic surfactant as dispersing agent. Cement pastes with water-to-cement ratio of 0.45 and additions of solid MWCNT by mass of cement up to 0.50 % were studied. Isothermal calorimetry results showed a clear retardation of the hydration of cement caused by the surfactant contained in the MWCNT dispersion. Nevertheless, thermogravimetric evaluations showed that once the hydration reaction resumed, the retardation effect of the surfactant did not have a negative impact on the amount of hydration products precipitated. It was concluded that the commercial MWCNT dispersion presents a good potential to be applied in oil well cement pastes.

关键词： carbon nanotubes     surfactant     retardation     combined water     C-S-H    

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Experimental investigation of liquid metal alloy based mini-channel heat exchanger for high power electronic

Manli LUO, Jing LIU

《能源前沿（英文）》 2013年 第7卷 第4期   页码 479-486 doi: 10.1007/s11708-013-0277-3

摘要： There is currently a growing demand for developing efficient techniques for cooling integrated electronic devices with ever increasing heat generation power. To better tackle the high-density heat dissipation difficulty within the limited space, this paper is dedicated to clarify the heat transfer behaviors of the liquid metal flowing in mini-channel exchangers with different geometric configurations. A series of comparative experiments using liquid metal alloy Ga68%In20%Sn12% as coolant were conducted under prescribed mass flow rates in three kinds of heat exchangers with varied geometric sizes. Meanwhile, numerical simulations for the heat exchangers under the same working conditions were also performed which well interpreted the experimental measurements. The simulated heat sources were all cooled down by these three heat dissipation apparatuses and the exchanger with the smallest channel width was found to have the largest mean heat transfer coefficient at all conditions due to its much larger heat transfer area. Further, the present work has also developed a correlation equation for characterizing the Nusselt number depending on Peclet number, which is applicable to the low Peclet number case with constant heat flux in the hydrodynamically developed and thermally developing region in the rectangular channel. This study is expected to provide valuable reference for designing future liquid metal based mini-channel heat exchanger.

关键词： heat exchanger     liquid metal     mini-channel     heat dissipation     heat transfer coefficient    

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Analysis of flow and heat transfer characteristics of porous heat-storage wall in greenhouse

OUYANG Li, LIU Wei

《能源前沿（英文）》 2008年 第2卷 第4期   页码 406-409 doi: 10.1007/s11708-008-0094-2

摘要： The flow and heat transfer characteristics of porous heat-storage wall in greenhouse are studied by using the one-dimensional steady energy two-equation model for saturated porous medium. The results show that the heat exchange between the air and the solid matrix of the porous heat-storage wall depends upon the inlet air velocity, the porosity and the permeability of porous medium, and the thermal conductivity of the solid matrix. Because the incidence of solar radiation on the porous heat-storage wall is not uniform, the new composite porous solar wall with different porosity is proposed to reduce the disadvantageous effect.

关键词： incidence     thermal conductivity     heat-storage     exchange     composite    

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Major applications of heat pipe and its advances coupled with sorption system: a review

Yang YU, Guoliang AN, Liwei WANG

《能源前沿（英文）》 2019年 第13卷 第1期   页码 172-184 doi: 10.1007/s11708-019-0610-6

摘要： Heat pipe utilizes continuous phase change process within a small temperature drop to achieve high thermal conductivity. For decades, heat pipes coupled with novel emerging technologies and methods (using nanofluids and self-rewetting fluids) have been highly appreciated, along with which a number of advances have taken place. In addition to some typical applications of thermal control and heat recovery, the heat pipe technology combined with the sorption technology could efficiently improve the heat and mass transfer performance of sorption systems for heating, cooling and cogeneration. However, almost all existing studies on this combination or integration have not concentrated on the principle of the sorption technology with acting as the heat pipe technology for continuous heat transfer. This paper presents an overview of the emerging working fluids, the major applications of heat pipe, and the advances in heat pipe type sorption system. Besides, the ongoing and perspectives of the solid sorption heat pipe are presented, expecting to serve as useful guides for further investigations and new research potentials.

关键词： heat pipe     sorption system     heat transfer     solid sorption heat pipe    

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标题 作者 时间 类型 操作

预制拼装箱梁现浇横隔梁水化热分析与控制研究

陈扬,钟瑶,郑开启,沈斌,孟少平

期刊论文

Hydration, microstructure and autogenous shrinkage behaviors of cement mortars by addition of superabsorbent

Beibei SUN, Hao WU, Weimin SONG, Zhe LI, Jia YU

期刊论文

混凝土的裂缝与控制

缪昌文,刘建忠,田倩

期刊论文

Thermodynamic analysis of ethanol synthesis from hydration of ethylene coupled with a sequential reaction

Jie Gao, Zhikai Li, Mei Dong, Weibin Fan, Jianguo Wang

期刊论文

The effect of SiO

Ismael FLORES-VIVIAN, Rani G.K PRADOTO, Mohamadreza MOINI, Marina KOZHUKHOVA, Vadim POTAPOV, Konstantin SOBOLEV

期刊论文

Field test on temperature field and thermal stress for prestressed concrete box-girder bridge

Baoguo CHEN, Rui DING, Junjie ZHENG, Shibiao ZHANG

期刊论文

Quantification of hydration products in cementitious materials incorporating silica nanoparticles

L. P. SINGH,A. GOEL,S. K. BHATTACHARYYA,G. MISHRA

期刊论文

Absorption heat pump for waste heat reuse: current states and future development

Zhenyuan XU, Ruzhu WANG

期刊论文

Effects of radiation and heat source/sink on unsteady MHD boundary layer flow and heat transfer over

Krishnendu Bhattacharyya

期刊论文

Heat-spreading analysis of a heat sink base embedded with a heat pipe

B. V. BORGMEYER, H. B. MA,

期刊论文

Application of entransy dissipation theory in heat convection

Mingtian XU, Jiangfeng GUO, Lin CHENG,

期刊论文

Effect of a commercial dispersion of multi walled carbon nanotubes on the hydration of an oil well cementing

Ocar Aurelio MENDOZA REALES,William C.PEARL Jr,Maria D. M. PAIVA,CristianeR. MIRANDA,Romildo Dias TOLEDO FILHO

期刊论文

Experimental investigation of liquid metal alloy based mini-channel heat exchanger for high power electronic

Manli LUO, Jing LIU

期刊论文

Analysis of flow and heat transfer characteristics of porous heat-storage wall in greenhouse

OUYANG Li, LIU Wei

期刊论文

Major applications of heat pipe and its advances coupled with sorption system: a review

Yang YU, Guoliang AN, Liwei WANG

期刊论文